Search results for "Thiophene derivatives"

showing 6 items of 6 documents

ChemInform Abstract: Indirect Regioselective Heteroarylation of Indoles Through a Friedel-Crafts Reaction with (E)-1,4-Diaryl-2-buten-1,4-diones.

2010

Abstract A two-step synthesis of 3-heteroaryl indoles has been developed. The first step of the sequence involves a Friedel–Crafts alkylation of indoles with 1,4-diaryl-2-buten-1,4-diones to give the corresponding indoles bearing a 1,4-dicarbonyl moiety. The reaction is catalyzed by InCl 3 and takes place with good yields. Cyclization of the diones under different Paal–Knorr conditions allows to prepare indoles substituted at the C3 position with 3-furanyl, 3-pyrrolyl- and 3-thienyl moieties.

ChemistryMoietyRegioselectivityGeneral MedicineAlkylationThiophene derivativesMedicinal chemistryFriedel–Crafts reactionPyrrole derivativesCatalysisChemInform
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Pyrene-benzoylthiophene Bichromophores as Selective Triplet Photosensitizers.

2006

Combination of the pyrene and benzoylthiophene units constitutes an interesting approach to design bichromophoric photosensitizers with increased intersystem crossing quantum yield and enhanced selectivity. The potential of this strategy has been illustrated in the present work by using a model photoisomerization reaction.

PhotoisomerizationChemistryMetals and AlloysQuantum yieldGeneral ChemistryGeneral MedicinePhotochemistryThiophene derivativesCatalysisSurfaces Coatings and FilmsElectronic Optical and Magnetic Materialschemistry.chemical_compoundIntersystem crossingMaterials ChemistryCeramics and CompositesPyreneEnhanced selectivityChemInform
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ChemInform Abstract: Oxidative (Cross-)Coupling Reactions Mediated by C-H Activation of Thiophene Derivatives by Using Molybdenum(V) Reagents.

2015

The use of MoCl5 renders possible the preparation of various synthetically important polycyclic thienoacenes.

chemistryMolybdenumReagentchemistry.chemical_elementGeneral MedicineOxidative phosphorylationThiophene derivativesCombinatorial chemistryCoupling reactionChemInform
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ChemInform Abstract: A Versatile Palladium/Triphosphane System for Direct Arylation of Heteroarenes with Chloroarenes at Low Catalyst Loading.

2010

The present new catalyst system can be used for the direct arylation of various heteroaromatic compounds at low palladium loadings.

chemistry.chemical_compoundTriphosphanechemistrychemistry.chemical_elementGeneral MedicineCombinatorial chemistryThiophene derivativesPyrrole derivativesCatalysisPalladiumChemInform
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ChemInform Abstract: Water-Soluble Palladium Nanoparticles: Click Synthesis and Applications as a Recyclable Catalyst in Suzuki Cross-Couplings in Aq…

2011

Polyethylene glycol-tagged macrocycle (I) is prepared by a three-fold copper-catalyzed [3 + 2] cycloaddition reaction.

chemistry.chemical_compoundWater solubleAqueous mediumChemistryPolymer chemistryPalladium nanoparticlesGeneral MedicinePolyethyleneThiophene derivativesRecyclable catalystCycloadditionChemInform
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From One-Pot NH-Sulfoximidations of Thiophene Derivatives to Dithienylethene-Type Photoswitches

2019

Thiophene NH-sulfoximines have been synthesized using a one-pot NH-sulfoximidation reaction of thiophenes. The reactivity of the products was investigated, and the developed protocols were used for the synthesis of a new class of dithienylethene-type photoswitches containing a sulfoximidoyl group.

chemistry.chemical_compoundchemistry010405 organic chemistryOrganic ChemistryThiopheneOrganic chemistryReactivity (chemistry)Physical and Theoretical Chemistry010402 general chemistry01 natural sciencesBiochemistryThiophene derivatives0104 chemical sciencesOrganic Letters
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